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A comparison between conventional macroscopic and microscopic scanning electrochemical methods to evaluate galvanic corrosion

Akid, R. and Mills, D. J. (2001) A comparison between conventional macroscopic and microscopic scanning electrochemical methods to evaluate galvanic corrosion. Corrosion Science. 43(7), pp. 1203-1216. 0010-938X.

Item Type: Article
Abstract: The scanning reference electrode technique (SRET) has been used to examine corrosion in a galvanic 'Kelocouple' system, being that of an explosively bonded joint comprising a tri-metallic sandwich of steel/aluminium/aluminium alloy. Quantitative results of local current densities in 4% sea water at room temperature have been obtained. These have been compared with results from two conventional macroscopic techniques for measuring galvanic current, namely zero resistance ammetry and polarisation curves. The SRET results were found to be at least an order of magnitude higher than the average results obtained using the macroscopic methods. Comparison between SRET current densities and corrosion (as obtained by the amount of aluminium in solution) showed good agreement. Whether attack predominated on the aluminium (nearer the steel) or the aluminium alloy (further from the steel) depended on the concentration of the sea water
Subjects: T Technology > TP Chemical technology > TP250 Industrial electrochemistry
T Technology > TA Engineering (General). Civil engineering (General) > TA418 Corrosion engineering
Creators: Akid, R and Mills, Douglas J
Publisher: Elsevier
Faculties, Divisions and Institutes: University Faculties, Divisions and Research Centres - OLD > School of Applied Sciences (to 2009) > Engineering (to 2009)
Faculties > Faculty of Arts, Science & Technology > Engineering
Date: 1 July 2001
Date Type: Publication
Page Range: pp. 1203-1216
Journal or Publication Title: Corrosion Science
Volume: 43
Number: 7
Language: English
DOI: https://doi.org/10.1016/S0010-938X(00)00091-3
ISSN: 0010-938X
Status: Published / Disseminated
Refereed: Yes
Related URLs:
URI: http://nectar.northampton.ac.uk/id/eprint/65

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